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a rare kaolinite-serpentine group mineral typically formed through the alteration of primary manganese silicates, including rhodonite, in metamorphosed manganese deposits.
Cotterell (2006) discovered caryopilite forming thin veinlets within a specimen of siliceous manganese ore in the collections of the National Museum of Wales. The specimen, labelled as from Nant-y-Gadwen, Rhiw, Llŷn, Gwynedd was acquired by the National Museum of Wales from Dr. A.W. Woodland in 1937. Dr. Woodland published a number of papers on the petrography of manganese ores of North Wales.